Light-induced symmetry changes in tiny crystals allow researchers to create materials with tailored properties

Scientists from the U.S. Department of Energy’s (DOE) Argonne National Laboratory (ANL) and SLAC National Accelerator Laboratory; the University of Chicago; the University of Vermont; Middlebury College; Brown University; Stanford University; and Northwestern University have observed that when semiconductor nanocrystals called quantum dots were exposed to short bursts of light, the symmetry of the crystal structure changed from a disordered state to a more organized one. The return of symmetry directly affected the electronic properties of the quantum dots by causing a decrease in the bandgap energy, which is the difference in energy that electrons need to jump from one state to another within a semiconductor material. This change can influence how well quantum dots conduct electricity and respond to electric fields. Part of this work was conducted at the Center for Nanoscale Materials, a DOE Office of Science user facility at ANL.