A new way to engineer composite materials

Researchers from the Department of Energy’s (DOE) Lawrence Berkeley National Laboratory (Berkeley Lab); the University of California, Berkeley; and Northwestern University have developed a way to engineer pseudo-bonds in materials. Instead of forming chemical bonds – which is what makes epoxies and other composites tough – the chains of molecules entangle in a way that is fully reversible. The researchers attached polystyrene chains to 100-nanometers-diameter silica particles to create “hairy particles.” These hairy particles self-assembled into a crystal-like structure, and the space available to each polystyrene chain depended on its position in the structure. While some chains became rigid under confinement, others ultimately disentangled and stretched. The result was a strong, tough, thin-film material, held firmly together by pseudo bonds of tangled polystyrene chains. The research was conducted, in part, at the Molecular Foundry, a DOE Office of Science user facility at Berkeley Lab.